Web[Cu (SCN)] (1), which can also be viewed as a 3-D network constructed by linkages of 2-D sheets and 1-D chains via unsupported CuI-CuI interactions. The CuI-CuI contact of 2.651 (4) A in 1 is the... WebApr 25, 2011 · Coprophilia definition, an obsessive interest in feces. See more.
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WebJan 10, 2024 · Theoretical calculations break down the attractive and repulsive forces associated with cuprophilicity, its spontaneous 4p-3d hybridization origin, and direction … WebMay 22, 2024 · Cuprophilicity is still under debate, while aurophilicity and argentophilicity are well recognized. I.-C. Chen, Y.-C. Tsai, and co-workers report in their Communication on page 9925 ff. the synthesis and characterization of two dodecacopper(I) chain-like complexes via intermolecular Cu–Cu coupling of two linear hexacopper monomers. Their …
WebDec 29, 2004 · To verify whether attractive metallophilic interactions exist in the dimer-of-dimers [Cu2(ophen)2]2(Hophen=1H-[1,10]phenanthrolin-2-one) (1), we designed and … WebAug 12, 2024 · @article{osti_1767060, title = {Piezochromism in the magnetic chalcogenide MnPS3}, author = {Harms, Nathan C. and Kim, Heung-Sik and Clune, Amanda J. and Smith, Kevin A. and O’Neal, Kenneth R. and Haglund, Amanda V. and Mandrus, David G. and Liu, Zhenxian and Haule, Kristjan and Vanderbilt, David and …
WebJul 26, 2024 · Compared with their THF-bound hexacopper(I) monomers and protonated ligands, these ligand-unsupported cuprophilic interactions are shown to be weak by Raman spectroscopy. DFT calculations suggest the ligand-unsupported cuprophilicity originate from weak attractive orbital interactions, and the strength is estimated to be 2.4 kcal mol-1 . WebNov 17, 2000 · DFT calculations suggest the ligand‐unsupported cuprophilicity orginate from weak attractive orbital interactions, and the strength is estimated to be 2.4 kcal/mol. View. Show abstract.
WebSep 15, 2024 · A solid AND logic stimuli-responsive material with bright nondestructive performance designed by sensitive cuprophilicity. / Shan, Xiao Chen; Jiang, Fei Long; Zhang, Hua Bin et al. In: Chemical Communications, Vol. 49, No. 87, 08.10.2013, p. 10227-10229. Research output: Contribution to journal › Article › peer-review
WebJan 7, 2005 · DFT calculations suggest the ligand‐unsupported cuprophilicity orginate from weak attractive orbital interactions, and the strength is estimated to be 2.4 kcal/mol. View. Show abstract. green cattle company madrasWebJan 10, 2014 · Three 2D luminescent isomeric porous coordination polymers are synthesized and characterized. Their luminescence properties can be modified by grinding and they can act as mechanochromic materials and their properties are probably related to the weak interactions of cuprophilicity and π–π interactions. Supporting Information … flow item typesWeb3⋯I) interactions, cuprophilicity, and Fig. 1 Crystal structure of the adduct with intermolecular Cu 3⋯I (π-acid⋯base) and Cu⋯Cu interactions (a) and N⋯H hydrogen bonds (b) green cat throw upWebNov 21, 2015 · Complex 2 emits strong phosphorescence at 77 K with maxima at 493 and 588 nm, which are tentatively attributed to the excited states 3LMMCT and 3MM, respectively. Based on the structural data, it is likely that weak intratrimeric (rather than intertrimeric) CuI···CuI interactions are responsible for the cuprophilicity-dependent … green cat timetable perthWebThe organic ligand 4-dpda is chosen to amplify the perturbation toward metallophilic interations for steric hindrance, and many of the molecular interactions of its multi- … flowitems flexsimWebDec 29, 2004 · To verify whether attractive metallophilic interactions exist in the dimer-of-dimers [Cu 2 (ophen) 2] 2 (Hophen=1H-[1,10]phenanthrolin-2-one) (1), we designed and synthesized a series of such [M 2 L 2] 2 structures by varying the d 10 metal and/or the ligand (M=Cu I or Ag I, L=ophen or obpy; Hobpy=1H-[2,2′]bipyridinyl-6-one), and have … green cat toy videoWebTheoretical calculations break down the attractive and repulsive forces associated with cuprophilicity, its spontaneous 4p–3d hybridization origin, and direction-dependent … flow it hardware